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KMID : 0895420010110010048
Journal of Korean Society of Occupational and Enviromental Hygiene
2001 Volume.11 No. 1 p.48 ~ p.55
Accuracy and Precision of Microwave Oven Digestion/Atomic Absorption Spectrophotometry for Analyzing Airborne Chromium Collected on MCE Filter in Plating Operation



Abstract
The purpose of this study was to evaluate the analytical accuracy and precision of microwave oven digestion/atomi absorption spectrophotometry (AAS) for analyzing airborne chromium collected on mixed cellulose ester membrane (M filter from the work environment, and to compare the accuracy and the precision with those of the National Institute for Occupational Safety and Health (NIOSH) Metho? #7024 hot plate digestion/AAS method. For this study, field air sample pairs were collected from a electroplating process, and spiked samples in a laboratory were prepared and using these samples. Two digestion methods were comp? and evaluated in terms of recovery rate and bias as indices of accuracy and coefficient of variation as a index of precision. The results and conclusions are as follows. In spiked samples, the accuracies (£¥ mean recoveries) of h? plate/AAS and microwave oven/AAS method were 97.19? 97.1£¥, respectively, and the precisions (pooled respectively, and the precisions (pooled coefficient of variance, CV_pooled) 6.93£¥ and 3.88£¥, respectively. The biases of hot plate an? microwave oven methods were 4.56 - 14.7£¥ and 2.2 - 7.? respectively. There was no statistically significant difference between hot plate and microwave oven methods recovery rates of spiked sample (p>0.05). Also, no statistically significant difference was shown among the concentrations of air samples determined by two method(p>0.05). In conclusion, microwave oven/AAS method h? excellent accuracy and precision, and advantages such as time-saving and simple procedure in comparison with th? classical NIOSH method. Therefore, this method can be use? widely to analyze airborne chromium collected on MCE filter from the work environments.
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